Analysis of Shape-memory Polymers with High Elastic Energy Storage Capacity

Ebna Zabir

Department of Mechanical Engineering

University of Rochester

Sputter Coating

Sputter coating is required for this sample due to electrical conductivity reasons. Sample are coated with 40 angstroms of gold particles.

Figure 3.0: Gold coated samples are ready for imagining in the Scanning Electron Microscope.

Secondary Electron Detector

The sample is imaged using the secondary electron detector within the scanning electron microscope. Figure 3.1 below illustrates the indentation at 397X magnification with 20kV accelerating voltage. Although it is an excellent image, the scanning electron microscope is not the best with determining the depth (Z height) and surface roughness of the sample; therefore, the Atomic Force Microscope is used for depth and surface roughness analysis.

Figure 3.1: An image of the indentation on the surface of the sample generated via the secondary electron detector.

Energy Dispersive Spectrometry

Energy Dispersive Spectrometry or EDS is a detector that sits within the Scanning Electron Microscope. It is used to identify element composition and chemical characterization of a sample. Figure 3.2 below shows an EDS of the polymer sample. Carbon is the highest content within the sample and it is followed by Oxygen, Gold and Molybdenum. Moreover, EDS is capable of mapping out each element with colour, which is shown in Figure 3.2.

Figure 3.2: Energy-dispersive X-ray spectroscopy of the sample.

 

Figure 3.3: Elemental and chemical composition maps of the sample.

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