Selected Honors & Awards
NRC Postdoctoral Fellowship, U.S. Naval Research Laboratory (2015-2017)
Robert L. Pigford Teaching Assistant Award, University of Delaware (2012)
CHE 150 - Green Energy
CHE 461 - Advanced Kinetics and Reactors Design
CO2 Reduction; Heterogeneous Catalysis; Catalyst Structure-Property Relationships; C1 Chemistry; Upgrading Light Alkanes.
Juneau, M.; Pope, C.; Liu, R.J.; Porosoff, M.D., "Support Acidity as a Descriptor for Reverse Water-Gas Shift Over Mo2C-Based Catalysts," Applied Catalysis A-General, 2021, 620, 118034. DOI:10.1016/j.apcata.2021.118034
Liu, R.J.; Ma, Z.; Sears, J.D.; Juneau, M.; Neidig, M.L.; Porosoff, M.D., "Identifying Correlations in Fischer-Tropsch Synthesis and CO2 hydrogenation over Fe-based ZSM-5 Catalysts," Journal of CO2 Utilization, 2020, 41, 101290. DOI:DOI:10.1016/j.jcou.2020.101290
Juneau, M.; Liu, R.J.; Peng, Y.; Malge, A.; Ma, Z.; Porosoff, M.D., "Characterization of Metal-elite Composite Catalysts: Determining the Environment of the Active Phase," ChemCatChem, 2020, 12, 1-28. DOI:org/10.1002/cctc.201902139
Morse, J.R.; Juneau, M.; Baldwin, J.W.; Porosoff, M.D.; Willauer, H.D., "Alkali Promoted Tungsten Carbide as a Selective Catalyst for the Reverse Water Gas Shift Reaction," Journal of CO2 Utilization, 2019, 35, 38-46. DOI: 10.1016/j.jcou.2019.08.024
Ma, Z.; Porosoff, M.D., "Development of Tandem Catalysts for CO2 Hydrogenation of Olefins," ACS Catalysis, 2019, 9, 3, 2639-2656. DOI.org/10.1021/acscatal.8b05060
Dixit, M.; Peng, X.; Porosoff, M.D.; Wilauer, H.D.; Mpourmpakis, G., "Elucidating the Role of Oxygen Coverage in CO2 Reduction on Mo2C," Catalysis Science & Technology, 2017, 7, 23, 5521-5529.
Porosoff, M.D.; Baldwin, J.W.; Peng, X.; Mpourmpakis, G.; Willauer, H.D., "Potassium-Promoted Molybdenum Carbide as a Highly Active and Selective Catalyst for CO2 Conversion to CO," Chemsuschem, 2017, 11, 2408-2415.
New catalysts for upgrading C1 and C2 resources (CO2, CO, CH4, C2H6) represent significant opportunities for efficient energy storage and low-cost production of plastics, chemicals and fuels. Understanding the relationships between chemical reactivity and catalyst electronic/structure properties are extremely important for developing catalysts that exploit particular reaction pathways. This approach requires controlled synthesis of catalysts combined with in situ techniques and theoretical calculations. In particular, target areas of research are three types of catalytic reactions for improved shale gas utilization and lowering CO2 emissions: (I) Catalyst development for CO2 hydrogenation, (II) Selective synthesis of light olefins from CO and H2 and (III) Catalytic dehydrogenation of light alkanes to olefins by CO2. Experimental work combines an mix of catalyst synthesis and characterization, reactor studies and in situ spectroscopy.